个人简介

1987 年本科毕业于东北师范大学化学系,1990 年中科院长春应用化学研究所硕士研究生,1995 年12 月莫斯科大学化学系弗鲁姆金电化学教研室获得副博士学位,1997 年 12 月北京大学化学学院博士后出站后到首都师范大学化学系工作,2000 年评定研究员职称,2006 年初到yl6809永利官网理学院化学系任教。

作为项目负责人承担了国家、北京市自然科学基金,教育部的“优秀青年教师计划”和“高等学校骨干教师资助计划”,北京市“科技新星”培养计划等 10 项。目前承担国家自然科学基金面上项目:扫描电化学显微镜方法研究自组装膜表面氢键协同作用,资助期限 2019.01-2022.12,直接经费 65 万。近 10 年已培养硕士 24 名,博士 12 名。目前在读硕士生 4 名、博士生 2 名。在电极表面的分子自组装膜构筑、表征及氢键电化学等电化学研究方面已发表 SCI 收录论文 61 篇。


研究领域和方向

自组装单分子膜电化学。从新研究方法的建立,研究体系选择与优化及研究内容提炼与深入等方面对自组装膜体系分子间弱相互作用进行研究。具体为运用扫描电化学显微镜方法(SECM)研究氢键、电化学调控氢键、π-π 相互作用、静电作用及离子对效应等对氢键行为影响的研究,并应用于电化学传感器的研究。

教育背景

1991-1995 莫斯科大学化学系,弗鲁姆金电化学教研室,副博士
1990-1991 中科院长春应用化学研究所 硕士
1983-1987 东北师范大学 化学系 学士

工作履历

2006-至今 yl6809永利官网,yl6809永利官网,教授
2000-2006 首都师范大学,化学系,研究员
1998-2000 首都师范大学,化学系,副教授
1996-1997 北京大学,化学与分子工程学院,博士后
1987-1990 东北林业大学,化学系,助教

研究成果

近些年本组研究生为第一作者发表论文如下:
1、N. Li, X. M. Huang, J. C. Chen, H. B. Shao*. Investigating the conversion from coordination bond to electrostatic interaction on self-assembled monolayer by SECM. Electrochimica Acta, 2022, 423, 140569 - 140572.
2、A. H Fan, J. C. Chen, N. Li, H. X Guo, X. Li, L. L. Zhang, H. B. Shao*. Probing Ca2+-induced electron transfer on the surface of self-assembled monolayer using SECM. J. Electroanal. Chem., 2022, 914, 116292 – 116300.
3、L. L. Zhang, N. Li, Z. Z. Chen, X. Li, A. H Fan, H. B. Shao*. Investigating the substitution of intermolecular hydrogen bonds on the surface of self-assembled monolayer by scanning electrochemical microscopy. J. Electroanal. Chem., 2022, 923, 116790 - 116795.
4、X. Li, N. Li, Z. Z. Chen, H. B. Shao*. Study of the electrostatic repulsion of the carboxylic surface in the diffusion layer by scanning electrochemical microscopy. J. Chin. Chem. Soc., 2022, 69, 1088 – 1095.
5、N. Li, J. C. Chen, X. M. Huang, H. X. Guo, X. Li, A. H. Fan, H. B. Shao*. Competition of ion-pair during the transition from hydrogen bonding to electrostatic interaction on self-assembled monolayer. Electrochimica Acta, 2021, 397, 139310 - 139321.
6、J. C. Chen, X. M. Huang, N. Li, H. X. Guo, Z. M. Gao, H. B. Shao*. Quantitative analysis of the hydrogen bond Interaction between tyrosine and a simulated cell membrane by SECM. J. Phys. Chem. C, 2021, 125, 410 - 418
7、X. M. Huang, J. C. Chen, C. X. Yan, H. X. Guo, H. B. Shao*. Probing Charge Reversal of Zwitterion at Defects on Self-Assembled Monolayers by Scanning Electrochemical Microscopy. J. Phys. Chem. C, 2020, 124, 8876 - 8884.
8、J. C. Chen, X. M. Huang, C. X. Yan, H. X. Guo, Z. M. Gao, H. B. Shao*. Controllable release of dopamine from simulated enzyme-containing biomembrane by biased potential. Analytica Chimica Acta, 2020, 1125, 135 - 143.
9、J. C. Chen, X. M. Huang, X. T. Fang, C. X. Yan, Z. M. Gao, H. B. Shao*. Disassembly of intermolecular hydrogen bond induced by cations on selfassembled monolayer. J. Electroanal. Chem., 2020, 876, 114476
10、X. M. Huang, J. C. Chen, C. X. Yan, H. B. Shao*. Probing a Reversible Cationic Switch on a Mixed Self-Assembled Monolayer Using Scanning Electrochemical Microscopy. Langmuir, 2019, 35, 10772 - 10779.
11、Q. Zheng, H. B. Shao*. Correlation between redox species adsorption and electron transfer kinetics of mildly oxidized graphene: A chronocoulometry and SECM study. Electrochemistry Communications, 2019,103, 83 - 87.
12、X. M. Huang, J. C. Chen, X. T. Fang, C. X. Yan, H. B. Shao*. Exploring the enhancement of electron tunneling induced by intermolecular interactions on surface of self-assembled monolayer. J. Electroanal. Chem., 2019, 837, 143 - 150.
13、C. X. Yan, X. M. Huang, J. C. Chen, H. X. Guo, H. B. Shao*. Study on Preferential Solvation of Water by Electrochemical Method. Electroanalysis, 2019, 31, 1 - 9.
14、X. M. Huang, Q. Zheng, X. T. Fang, H. B. Shao*. Probing Qualitative Change in Intermolecular Forces from Hydrogen Bonding to Electrostatic Interaction on the Surface of Self-Assembled Monolayer. Journal of The Electrochemical Society, 2018, 165 (5), H240 - H246.
15、Q. Zheng, H. B. Shao*. Influence of intermolecular H-bonding on the acid-base interfacial properties of -COOH and ferrocene terminated SAM. J. Electroanal. Chem., 2018, 829, 88 - 94.