个人简介
中国化学工程研究生教育联盟理事会副理事长,《化工进展》第十一届编委会成员。指导学生获化工设计大赛全国一等奖等10余项。获校级“师德先进个人”称号和 “三育人先进个人”称号。获校级优秀教育教学成果奖二等奖2项,中国石油与化工教育教学成果奖二等奖1项,全国石油和化工教育优秀教学团队2个。
承担《化工设计与实践(I、II)》本科生课程,《催化科学与技术》研究生课程。开展了甲烷制合成气、甲醇合成与催化转化、生物质高效催化转化、光电催化转化与利用等方面科学研究。在甲醇合成与催化转化方面,开发了高活性、高稳定性的CH4/CO2重整催化剂、甲醇合成催化剂以及二甲醚合成催化剂(γ-Al2O3、HZSM-5/MCM-41。所开发的万吨级二甲醚产业化技术在河北、陕西、新疆等地得到工业化应用。在生物质高效催化转化方面,将离子液体、介孔超细粒子和磁分离相结合,提出了磁性介孔结构型超细粒子负载离子液体催化剂,实现了生物柴油合成过程反应-传质-磁分离过程耦合与高效转化。将聚醚链温敏特性与离子液体相结合,提出了温敏型双亲性离子液体酸催化剂新概念,实现了生物柴油合成过程反应-传质-相分离过程耦合与高效转化。在光电催化转化与利用方面,利用微乳液界面效应,提出了可控制备核壳型磁性纳米复合光催化材料的微乳液媒介溶胶凝胶方法;将光催化与磁分离耦合,提出了气升式悬浮光催化水处理方法,解决了液相光催化过程中催化效率低的问题。利用钴硫(硒)化合物与纳米碳协同作用,开展了高活性、高稳定性的钴基化合物/纳米碳复合材料的结构调控。利用原位还原炭化与化学置换相结合制备了低铂CoFeO@Pt@介孔碳核壳型材料,有效提高Pt利用率及其电催化甲醇氧化活性、催化剂稳定性和抗CO中毒性,为直接甲醇燃料电池商业化应用奠定基础。
研究领域和方向
新型催化材料设计与制备绿色合成过程与工艺新型反应器设计与开发能源化工
教育背景
1998.02-2001.06 天津大学 化工学院 博士 1995.09-1998.02 天津大学 理学院 硕士 1991.09-1995.06 天津大学 应用化学系 学士
工作履历
2022.10-至今 yl6809永利官网 yl6809永利官网 教授 副院长 2020.03-2022.09 yl6809永利官网 yl6809永利官网 副教授 副院长 2019.03-2020.02 yl6809永利官网 yl6809永利官网 副教授 院长助理 2016.06-2019.03 yl6809永利官网 yl6809永利官网 副教授 系主任/专业责任教授/中心教学主任 2004.06-2016.05 yl6809永利官网 化工与环境学院 副教授 副系主任 2002.01-2004.05 清华大学 化学工程系 博士后
研究成果
主持国家自然科学基金项目3项、世界银行援助项目1 项,承担企业合作项目10余项;参与国家自然科学基金项目、国际科技合作项目等3项。迄今在国内外学术刊物及会议上发表学术论文100余篇,其中SCI收录40余篇,EI收录20余篇,获授权专利5项。 代表性成果如下: 1.Wang Tong, He Jianting, Wu Qin*, Yu Yunqi, Chen Kangcheng*, Shi Daxin Zhang Yaoyuan, Li Hansheng*. Winterberries-like 3D network of N-doped porous carbon anchoring on N-doped carbon nanotubes for highly efficient platinum-based catalyst in methanol electrooxidation. Carbon, 2022, 201: 200-211 2.Cheng Yaran, Chen Jing, Wang Tong, Wu Qin*, Shi Daxin, Zhang Yaoyuan, Chen Kangcheng, Li Hansheng*. Magnetically-separable acid-resistant CoFe2O4@Polymer@MIL-100 core-shell catalysts for the acetalization of benzaldehyde and methanol. Journal of colloid and interface science, 2022, 629: 571-581 3.Wu Qin*, Sun Yan, Wang Wei, Tian Shuyao, Ouyang Mengjie, Chen Kangcheng*, Shi Daxin, Zhang Yaoyuan, Li Hansheng*, Zhao Zhiping. Block copolymer pervaporation membranes with microphase separated structures for ethyl acetate separation. Separation and purification technology, 2022, 298: 121654 4.Ren Yujing, Chen Kangcheng*, Zhang Yaoyuan, Shi Daxin, Wu Qin, Liang Dongxia, Hu Chenxing, Li Hansheng*. N-doped carbon confined CoFe@Pt nanoparticles with robust catalytic performance for the methanol oxidation reaction. Journal of materials chemistry A, 2022,10: 13345-13354. 5.Wu Qin*, Guo Yanyan, Shang Jiqing, Shi Daxin, Zhang Yaoyuan, Chen Kangcheng, Li Hansheng*, Zhao Yun, Jiao Qingze. Synthesis of polyoxymethylene dimethyl ethers from formaldehyde and dimethoxymethane by the coupling of extraction and catalytic reaction. Chemical engineering science, 2022, 253: 117521 6.Su Pengju, Jiao Qingze, Li Hansheng*, Li Yongjian, Liu Xiufeng, Wu Qin*, Shi Daxin, Zhao Yun, Wang Tong, Wang Wei. Rational Design of NiCo2S4 Quantum Dot-Modified Nitrogen-Doped Carbon Nanotube Composites as Robust Pt-Free Electrocatalysts for Dye-Sensitized Solar Cells. ACS applied energy materials, 2021, 4: 4344-4354 7.Yang Wang, Li Hansheng*, Wu Qin*, Ren Yujing, Shi Daxin, Zhao Yun, Jiao Qingze. Functionalized Core-Shell Polystyrene Sphere-Supported Alkaline Imidazolium Ionic Liquid: An Efficient and Recyclable Catalyst for Knoevenagel Condensation. ACS sustainable chemistry & engineering, 2020, 8: 18126-18137 8.Fang Zhuqing, Shi Daxin*, Lin Na, Li Airu, Wu Qin, Wang Qiqi, Zhao Yun, Feng Caihong, Jiao Qingze, Li Hansheng*. Probing the synergistic effect of Mo on Ni-based catalyst in the hydrogenation of dicyclopentadiene. Applied Catalysis A, General, 2019,574:60-70 9.Li Yongjian, Liu Xiufeng, Li Hansheng*, Shi Daxin, Jiao Qingze, Zhao Yun, Feng Caihong, Bai Xiaoping, Wang Hongxia, Wu Qin*. Rational design of metal organic framework derived hierarchical structural nitrogen doped porous carbon coated CoSe/nitrogen doped carbon nanotubes composites as a robust Pt-free electrocatalyst for dye-sensitized solar cells. Journal of Power Sources,2019,422:122-130 10.Ren Yujing, Li Hansheng*, Yang Wang, Shi Daxin, Wu Qin, Zhao Yun, Feng Caihong, Liu Hongbo, Jiao Qingze*. Alkaline Ionic Liquids Immobilized on Protective Copolymers Coated Magnetic Nanoparticles: An Efficient and Magnetically Recyclable Catalyst for Knoevenagel Condensation. Industrial & Engineering Chemistry Research, 2019, 58(8): 2824-2834 11.Yuan Hong,Liu Jia, Li Hansheng*,Li Yongjian, Liu Xiufeng, Shi Daxin,Wu Qin, Jiao Qingze*. Graphitic carbon nitride quantum dots decorated three-dimension graphene as an efficient metal-free electrocatalyst for triiodide reduction. Journal of Materials Chemistry A, 2018, 6:5603-5607 12.Yuan Hong, Liu Jia, Li Hansheng*, Su Kuo, Liu Xiufeng, Li Yongjian, Shi Daxin, Wu Qin, Zhao Yun, Jiao Qingze*. Rational integration of hierarchical structural CoS1.097 nanosheets-reduced graphene oxide nanocomposites with enhanced electrocatalytic performance for triiodide reduction. Carbon, 2018, 126: 514-521 13.Yuan Hong, Jiao Qingze, Liu Jia, Liu Xiufeng, Li Yongjian, Shi Daxin, Wu Qin, Zhao Yun, Li Hansheng*. Facile synthesis of Co0.85Se nanotubes/reduced graphene oxide nanocomposite as Pt-free counter electrode with enhanced electrocatalytic performance in dye-sensitized solar cells. Carbon, 2017, 122: 381-388 14.Yuan Hong, Liu Jia, Jiao Qingze*, Li Yongjian, Liu Xiufeng, Shi Daxin, Wu Qin, Zhao Yun, Li Hansheng*. Sandwich-like octahedral cobalt disulfide-reduced graphene oxide as an efficient Pt-free electrocatalyst for high-performance dye-sensitized solar cells. Carbon, 2017, 119:225-234 15.Yuan Hong, Jiao Qingze, Liu Jia, Liu Xiufeng, Yang Haoyi, Zhao Yun, Wu Qin, Shi daxin, Li Hansheng*. Ultrathin-walled Co9S8 nanotube/reduced graphene oxide compositeas an efficient electrocatalyst for the reduction of triiodide. Journal of Power Sources, 2016, 336, 132-142 16.Yuan Hong, Jiao Qingze, Zhang Shenli, Zhao Yun, Wu Qin, Li Hansheng*. In situ chemical vapor deposition growth of carbon nanotubes on hollow CoFe2O4 as an efficient and low cost counter electrode for dye-sensitized solar cells. Journal of Power Sources, 2016, 325, 417-426 17.Hu Ju, Li Hansheng, Wu Qin*, Zhao Yun, Jiao Qingze. Synthesis of TiO2 nanowire/reduced graphene oxide nanocomposites and their photocatalytic performances. Chemical Engineering Journal, 2015, 263: 144-150 18.Wu Qin, Wang Min, Hao Yu, Li Hansheng*, Zhao Yun, Jiao Qingze. Synthesis of Polyoxymethylene Dimethyl Ethers Catalyzed by Bronsted Acid Ionic Liquids with Alkanesulfonic Acid Groups. Industrial & Engineering Chemistry Research, 2014, 53(42): 16254-16260 19.Zhang Yaping, Jiao Qingze, Zhen Bin, Wu Qin, Li Hansheng*. Transesterification of glycerol trioleate catalyzed by basic ionic liquids immobilized on magnetic nanoparticles: Influence of pore diffusion effect. Applied Catalysis A: General, 2013, 453:327-333 20.Wu Qin, Wan Hualin, Li Hansheng*, Song Haoran, Chu Tonghua. Bifunctional temperature-sensitive amphiphilic acidic ionic liquids for preparation of biodiesel. Catalysis Today, 2013, 200:74-79 21.Li Hansheng*, He Shichao, Ma Ke, Wu Qin, Jiao Qingze, Sun Kening. Micro-mesoporous composite molecular sievesH-ZSM-5/MCM-41 for methanol dehydration to dimethyl ether: Effect of SiO2/Al2O3 ratio in H-ZSM-5. Applied Catalysis A, 2013, 450:152-159 22.Zhen Bin, Li Hansheng, Jiao Qingze*, Li Yuan, Wu Qin, Zhang Yaping. SiW12O40-Based Ionic Liquid Catalysts: Catalytic Esterification of OleicAcid for Biodiesel Production. Industrial & Engineering Chemistry Research, 2012, 51(31):10374-10380 23.Zhen Bin, Jiao Qingze, Zhang Yaping, Wu Qin, Li Hansheng*. Acidic ionic liquid immobilized on magnetic mesoporous silica: preparation and catalytic performance in esterifications. Applied Catalysis A, 2012, 445-446:239-245 24.Li Hansheng, Zhang Yaping, Wang Shiying, Wu Qin, Liu Changhao. Study on nanomagnets supported TiO2 photocatalysts prepared by a sol-gel process in reverse microemulsion combining with solvent-thermal technique. Journal of Hazardous Materials, 2009, 169:1045-1053